The role of manganese dioxide in the secondary pollution of freshwater reservoirs (according to experimental modeling data)
https://doi.org/10.55959/MSU0579-9406-4-2023-63-2-152-156
Abstract
Experimental modeling of reductive dissolution during periods of hypoxia in freshwater reservoirs of manganese (IV) oxyhydroxides from bottom sediments, one of the main components, along with iron (III) oxyhydroxides, causing secondary pollution of the water column, was carried out. It was shown that in the hypoxia periods, not only dissolved forms of manganese can accumulate in the water column, but also trace elements sorbed on manganese(IV) oxyhydroxides. The mass ratios to manganese of trace elements-impurities passing into solution Δ[i]/ Δ[Mn]·103 were estimated: Li 0.41, Rb 1.65, Cs 0.010, Sr 31.7, Ba 50.3, Co 0.093, Ni 0.65, Сd 0.046, Y 0.070, La 0.030, Ce 0.086, Tl 0.015, U 0.23.
About the Authors
A. V. SavenkoRussian Federation
Alla V. Savenko
Moscow
V. S. Savenko
Russian Federation
Vitaly S. Savenko
Moscow
References
1. Богуш А.А., Аношин Г.Н. Формы нахождения элементов в окружающей среде и методы их исследования// Химический анализ в геологии и геохимии. Глава 6. Новосибирск: Академическое изд-во «Гео», 2016. С.125–146.
2. Лурье Ю.Ю. Унифицированные методы анализа вод. М.: Химия, 1971.
3. Савенко В.С. Полуэмпирическая математическая модель вторичного загрязнения водоемов растворенными формами железа и марганца // Водные ресурсы. 2016. Т. 43, № 6. С. 608–619.
4. Хатчинсон Д. Лимнология. М.: Прогресс, 1969.
5. Baharim N.H., Ismail R., Omar M.H. Effects of thermal stratification on the concentration of iron and manganese in a tropical water supply reservoir // Sains Malaysiana. 2011. Vol. 40, № 8. Р. 821–825.
6. Gibson J.A.E., Vincent W.F., Van Hove P., Belzile C. Geochemistry of ice-covered, meromictic Lake A in the Canadian High Arctic // Aquatic Geochem. 2002. Vol. 8, №2. P. 97–119.
7. Hamilton-Taylor J., Davison W. Redox-driven cycling of trace elements in lakes// Physics and Chemistry of Lakes. Berlin: Springer-Verlag, 1995. P.217–263.
Review
For citations:
Savenko A.V., Savenko V.S. The role of manganese dioxide in the secondary pollution of freshwater reservoirs (according to experimental modeling data). Moscow University Bulletin. Series 4. Geology. 2023;(2):152-156. (In Russ.) https://doi.org/10.55959/MSU0579-9406-4-2023-63-2-152-156












